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Material testing for lithium-ion batteries

By Paul Heney | December 3, 2021

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Freudenberg Sealing Technologies has expanded its material testing capabilities to include performance and compatibility evaluations of the rubber, elastomers and thermoplastics used to seal and safely maintain lithium-ion batteries. The company has installed sophisticated equipment and adopted new testing protocols in its Plymouth, Mich., Central Laboratory that will provide conclusive data on which materials optimally resist breakdown from constant exposure to harsh electrolytic solutions. Such data has not been readily available in the private sector until now.

Freudenberg Sealing Technologies continues to build its lithium-ion battery expertise with the installation of a sophisticated Isolation and Containment Chamber in its Plymouth Central Laboratory. The chamber allows the company to safely conduct exposure testing on materials that come in contact with aggressive lithium electrolytic solutions. From left, chemists Roger Natividad and Michael Saruna set up equipment inside the chamber.

The centerpiece of the six-figure investment is a specially designed Isolation and Containment Chamber (IsoC) that allows technicians to safely conduct exposure testing using the very aggressive lithium electrolytic solutions found in lithium-ion battery cells. These solutions are volatile, toxic and flammable when exposed to oxygen and ambient air moisture. The IsoC, a six-by-three-by-three-foot, two-chambered glass and steel enclosure, allows chemists to work in a controlled, inert and moisture-free environment.

In addition, Freudenberg Sealing Technologies also invested in a sophisticated telemetry control system that facilitates remote IsoC monitoring of the active work 24/7, head-to-toe protective gear and special respirators for chemists, non-reactive, nickel-based immersion vessels, a safety monitoring and alarm system and electrolytic solutions costing thousands of dollars per gallon.

“What we can now offer customers is design security based on scientific data,” said F. Joseph Walker, Director Research & Development for Freudenberg Sealing Technologies in the Americas. “We have taken this proactive step on behalf of our customers and in response to a growing use of lithium-ion batteries in diverse applications. Previous efforts have been conducted to determine the impact of materials on the electrolyte. This work focuses upon the impact the electrolyte has on the materials.”

A growing market
Multiple analyst forecasts project that the lithium-ion battery market will experience double-digit growth during the next five years based on increasing battery use in the automotive, construction agriculture, mining, commercial truck, recreational vehicle, ship, train and electronics industries. In response, the lithium-ion battery developers are constantly exploring ways to make these sustainable energy devices more powerful, more robust and faster during recharging cycles. Electrolytic solutions have a direct impact on these performance issues. New and enhanced electrolytic solvents are being continuously introduced. While these solvents can result in a faster exchange of lithium ions between the anode and cathode sides of a battery cell – thus ultimately impacting energy discharge ad recharge rates — they also expose seals, gaskets and other battery components to a constant mix of reactive, flammable, caustic and hazardous chemicals.

Freudenberg has spent decades performing comprehensive physical and analytical material testing to document the performance and compatibility of materials that are exposed to different fluids, materials and stress conditions. The database the company has assembled from the results provides specification guidance and material benchmarks for the components it sells to customers.

Lithium-ion material testing, however, requires a unique set of inputs to safely succeed. The new equipment and test methodology being used in the Central Laboratory provides these inputs.

New testing, new requirements
“All of our exposure testing must be performed inside the IsoC in an oxygen-free, moisture-free environment,” said Freudenberg Sealing Technologies’ Michael Saruna, the Central Laboratory chemist who is in charge of material testing in electrolytic solutions. “Electrolytic solution exposed to air can result in a hazardous situation, so we had to take safety and our ability to maintain a controlled environment into account during the design of the IsoC.”

The dual chambers of the IsoC allow Saruna to install test samples in the first chamber, purge all air, oxygen and moisture from that space and then move them to the second, larger IsoC chamber for exposure testing. Materials will be immersed electrolytic solution for at least 1,000 hours, then decontaminated to insure they are safe for removal from the IsoC. They will then be subjected to the company’s standard physical and analytical test methodologies.

Freudenberg will use two electrolytic solutions in its immersion testing — one that is commonly used in lithium-ion battery cells and one that has been manufactured as a control. The company will test families of materials, beginning with its own unique and proprietary materials and then moving on to test commercially available materials that are used in these batteries.

“Benchmarking will provide us with the ability to spot gaps in compatibility and performance,” Walker said. “Then we can develop material programs and components to fill those gaps.”

Safety first
The risks associated with testing lithium-ion battery materials exposed to electrolytic solutions are real, and the cost of controlling them is one of the reasons only a handful of universities are the only other organizations to conduct such testing. The Central Laboratory team redesigned safety standards to include as many safety precautions as possible. Full protective gear is required when handling the electrolytic solutions. First aid kits were stocked with special treatments that counter the caustic chemicals found in lithium electrolyte solutions. An alarm system is in place to monitor for spills, leakage, gas formation or other hazards. One of the most significant safety features is the ability of laboratory chemists to monitor the immersion samples remotely anytime and anywhere using a laptop computer, phone or tablet.

“We are committed to the safety of our employees and to the material needs of our customers,” Walker said. “We are performing this critical material testing in a protected, safe working environment. We will be able to offer our customers critical compatibility and performance data that will likely influence their material choices.”

Freudenberg Sealing Technologies
fst.com

 


Filed Under: Green engineering
Tagged With: freudenbergsealingtechnologies
 

About The Author

Paul Heney

Paul J. Heney, the VP, Editorial Director for Design World magazine, has a BS in Engineering Science & Mechanics and minors in Technical Communications and Biomedical Engineering from Georgia Tech. He has written about fluid power, aerospace, robotics, medical, green engineering, and general manufacturing topics for nearly 25 years. He has won numerous regional and national awards for his writing from the American Society of Business Publication Editors.

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