Design World

  • Home
  • Technologies
    • ELECTRONICS • ELECTRICAL
    • Fastening • joining
    • FLUID POWER
    • LINEAR MOTION
    • MOTION CONTROL
    • SENSORS
    • TEST & MEASUREMENT
    • Factory automation
    • Warehouse automation
    • DIGITAL TRANSFORMATION
  • Learn
    • Tech Toolboxes
    • Learning center
    • eBooks • Tech Tips
    • Podcasts
    • Videos
    • Webinars • general engineering
    • Webinars • Automated warehousing
    • Voices
  • LEAP Awards
  • 2025 Leadership
    • 2024 Winners
    • 2023 Winners
    • 2022 Winners
    • 2021 Winners
  • Design Guides
  • Resources
    • Subscribe
    • 3D Cad Models
      • PARTsolutions
      • TraceParts
    • Digital Issues
      • Design World
      • EE World
    • Engineering diversity
    • Trends
  • Supplier Listings
  • Advertise
  • Subscribe

Laying Down a Discerning Membrane

By atesmeh | October 4, 2013

One of the thinnest membranes ever made is also highly discriminating when it comes to the molecules going through it. Engineers at the University of South Carolina have constructed a graphene oxide membrane less than 2 nanometers thick with high permeation selectivity between hydrogen and carbon dioxide gas molecules.

The selectivity is based on molecular size, the team reported in the journal Science. Hydrogen and helium pass relatively easily through the membrane, but carbon dioxide, oxygen, nitrogen, carbon monoxide and methane permeate much more slowly.

“The hydrogen kinetic diameter is 0.289 nm, and carbon dioxide is 0.33 nm. The difference in size is very small, only 0.04 nm, but the difference in permeation is quite large” said Miao Yu, a chemical engineer in USC’s College of Engineering and Computing who led the research team. “The membrane behaves like a sieve. Bigger molecules cannot go through, but smaller molecules can.”

In addition to selectivity, what’s remarkable about the USC team’s result is the quality of the membrane they were able to craft on such a small scale. The membrane is constructed on the surface of a porous aluminum oxide support. Flakes of graphene oxide, with widths on the order of 500 nm but just one carbon atom thick, were deposited on the support to create a circular membrane about 2 square centimeters in area.

The membrane is something of an overlapping mosaic of graphene oxide flakes. It’s like covering the surface of a table with playing cards. And doing that on a molecular scale is very hard if you want uniform coverage and no places where you might get “leaks.” Gas molecules are looking for holes anywhere they can be found, and in a membrane made up of graphene oxide flakes, there would be two likely places: holes within the flakes, or holes between the flakes.

It’s the spaces between flakes that have been a real obstacle to progress in light gas separations. That’s why microporous membranes designed to distinguish in this molecular range have typically been very thick. “At least 20 nm, and usually thicker,” said Miao. Anything thinner and the gas molecules could readily find their way between non-uniform spaces between flakes.

Miao’s team devised a method of preparing a membrane without those “inter-flake” leaks. They dispersed graphene oxide flakes, which are highly heterogeneous mixtures when prepared with current methods, in water and used sonication and centrifugation techniques to prepare a dilute, homogeneous slurry. These flakes were then laid down on the support by simple filtration.

Their thinnest result was a 1.8-nm-thick membrane that only allowed gas molecules to pass through holes in the graphene oxide flakes themselves, the team reported. They found by atomic force microscopy that a single graphene oxide flake had a thickness of approximately 0.7 nm. Thus, the 1.8-nm-thick membrane on aluminum oxide is only a few molecular layers thick, with molecular defects within the graphene oxide that are essentially uniform and just a little too small to let carbon dioxide through easily.

The advance has a range of potential applications. With widespread concerns about carbon dioxide as a greenhouse gas, the efficient separation of carbon dioxide from other gases is a high research priority. Moreover, hydrogen represents an integral commodity in energy systems involving, for example, fuel cells, so purifying it from gas mixtures is also an active area of interest.

Yu also notes that the dimensions of the molecular sieve are on the order of the size of water, so, for example, purifying the copious amounts of tainted water produced by hydraulic fracturing (fracking) is another possibility.

Being able to reduce membrane thickness – and by an order of magnitude – is a big step forward, Yu said. “Having membranes so thin is a big advantage in separation technology,” he said. “It represents a completely new type of membrane in the separation sciences.”

You Might Also Like


Filed Under: Rapid prototyping

 

LEARNING CENTER

Design World Learning Center
“dw
EXPAND YOUR KNOWLEDGE AND STAY CONNECTED
Get the latest info on technologies, tools and strategies for Design Engineering Professionals.
Motor University

Design World Digital Edition

cover

Browse the most current issue of Design World and back issues in an easy to use high quality format. Clip, share and download with the leading design engineering magazine today.

EDABoard the Forum for Electronics

Top global problem solving EE forum covering Microcontrollers, DSP, Networking, Analog and Digital Design, RF, Power Electronics, PCB Routing and much more

EDABoard: Forum for electronics

Sponsored Content

  • Sustainability, Innovation and Safety, Central to Our Approach
  • Why off-highway is the sweet spot for AC electrification technology
  • Looking to 2025: Past Success Guides Future Achievements
  • North American Companies Seek Stronger Ties with Italian OEMs
  • Adapt and Evolve
  • Sustainable Practices for a Sustainable World
View More >>
Engineering Exchange

The Engineering Exchange is a global educational networking community for engineers.

Connect, share, and learn today »

Design World
  • About us
  • Contact
  • Manage your Design World Subscription
  • Subscribe
  • Design World Digital Network
  • Control Engineering
  • Consulting-Specifying Engineer
  • Plant Engineering
  • Engineering White Papers
  • Leap Awards

Copyright © 2025 WTWH Media LLC. All Rights Reserved. The material on this site may not be reproduced, distributed, transmitted, cached or otherwise used, except with the prior written permission of WTWH Media
Privacy Policy | Advertising | About Us

Search Design World

  • Home
  • Technologies
    • ELECTRONICS • ELECTRICAL
    • Fastening • joining
    • FLUID POWER
    • LINEAR MOTION
    • MOTION CONTROL
    • SENSORS
    • TEST & MEASUREMENT
    • Factory automation
    • Warehouse automation
    • DIGITAL TRANSFORMATION
  • Learn
    • Tech Toolboxes
    • Learning center
    • eBooks • Tech Tips
    • Podcasts
    • Videos
    • Webinars • general engineering
    • Webinars • Automated warehousing
    • Voices
  • LEAP Awards
  • 2025 Leadership
    • 2024 Winners
    • 2023 Winners
    • 2022 Winners
    • 2021 Winners
  • Design Guides
  • Resources
    • Subscribe
    • 3D Cad Models
      • PARTsolutions
      • TraceParts
    • Digital Issues
      • Design World
      • EE World
    • Engineering diversity
    • Trends
  • Supplier Listings
  • Advertise
  • Subscribe
We use cookies to personalize content and ads, to provide social media features, and to analyze our traffic. We share information about your use of our site with our social media, advertising, and analytics partners who may combine it with other information you’ve provided to them or that they’ve collected from your use of their services. You consent to our cookies if you continue to use this website.OkNoRead more