Design World

  • Home
  • Technologies
    • 3D CAD
    • Electronics • electrical
    • Fastening & Joining
    • Factory automation
    • Linear Motion
    • Motion Control
    • Test & Measurement
    • Sensors
    • Fluid power
  • Learn
    • Ebooks / Tech Tips
    • Engineering Week
    • Future of Design Engineering
    • MC² Motion Control Classrooms
    • Podcasts
    • Videos
    • Webinars
  • LEAP AWARDS
  • Leadership
    • 2022 Voting
    • 2021 Winners
  • Design Guide Library
  • Resources
    • 3D Cad Models
      • PARTsolutions
      • TraceParts
    • Digital Issues
      • Design World
      • EE World
    • Women in Engineering
  • Supplier Listings

Shape-Shifting Organic Crystals Use Memory to Improve Plastic Electronics

By University of Illinois at Urbana-Champaign | January 26, 2018

Share

Illinois chemistry and biomolecular engineering professor Ying Diao, right, and graduate student Hyunjoong Chung are part of a team that has identified a mechanism that triggers shape-memory in organic crystals used in plastic electronics. Image credit: L. Brian Stauffer

Researchers have identified a mechanism that triggers shape-memory phenomena in organic crystals used in plastic electronics. Shape-shifting structural materials are made with metal alloys, but the new generation of economical printable plastic electronics is poised to benefit from this phenomenon, too. Shape-memory materials science and plastic electronics technology, when merged, could open the door to advancements in low-power electronics, medical electronics devices and multifunctional shape-memory materials.

The findings are published in the journal Nature Communications and confirm the shape-memory phenomenon in two organic semiconductors materials.

Devices like the expandable stents that open and unblock clogged human blood vessels use shape-memory technology. Heat, light and electrical signals, or mechanic forces pass information through the devices telling them to expand, contract, bend and morph back into their original form – and can do so repeatedly, like a snake constricting to swallow its dinner. This effect works well with metals, but remains elusive in synthetic organic materials because of the complexity of the molecules used to create them.

“The shape-memory phenomenon is common in nature, but we are not really sure about nature’s design rules at the molecular level,” said professor of chemical and biomolecular engineering and co-author of the study, Ying Diao. “Nature uses organic compounds that are very different from the metal alloys used in shape-memory materials on the market today,” Diao said. “In naturally occurring shape-memory materials, the molecules transform cooperatively, meaning that they all move together during shape change. Otherwise, these materials would shatter and the shape change would not be reversible and ultrafast.”

The discovery of the shape-memory mechanism in synthetic organic material was quite serendipitous, Diao said. The team accidentally created large organic crystals and was curious to find out how they would transform given heat.

“We looked at the single crystals under a microscope and found that the transformation process is dramatically different than we expected,” said graduate student and co-author Hyunjoong Chung. “We saw concerted movement of a whole layer of molecules sweeping through the crystal that seem to drive the shape-memory effect – something that is rarely observed in organic crystals and is therefore largely unexplored.”

This unexpected observation led the team to want to explore the merger between shape-memory materials science and the field of organic electronics, the researchers said. “Today’s electronics are dependent on transistors to switch on and off, which is a very energy-intensive process,” Diao said. “If we can use the shape-memory effect in plastic semiconductors to modulate electronic properties in a cooperative manner, it would require very low energy input, potentially contributing to advancements in low-power and more efficient electronics.”

The team is currently using heat to demonstrate the shape-memory effect, but are experimenting with light waves, electrical fields and mechanical force for future demonstrations. They are also exploring the molecular origin of the shape-memory mechanism by tweaking the molecular structure of their materials. “We have already found that changing just one atom in a molecule can significantly alter the phenomenon,” Chung said.

The researchers are very excited about the molecular cooperativity aspect discovered with this research and its potential application to the recent Nobel Prize-winning concept of molecular machines, Diao said. “These molecules can change conformation cooperatively at the molecular level, and the small molecular structure change is amplified over millions of molecules to actuate large motion at the macroscopic scale.”


Filed Under: Materials • advanced

 

Related Articles Read More >

Self-lubricating and wear-resistant: igus bar stock for food, continuous operation and high media resistance
Minnesota Rubber and Plastics announces plans for new Innovation Center
The importance of resin selection
EXE014 - Image 1
Composite materials help place Italian race team in pole position

DESIGN GUIDE LIBRARY

“motion

Enews Sign Up

Motion Control Classroom

Design World Digital Edition

cover

Browse the most current issue of Design World and back issues in an easy to use high quality format. Clip, share and download with the leading design engineering magazine today.

EDABoard the Forum for Electronics

Top global problem solving EE forum covering Microcontrollers, DSP, Networking, Analog and Digital Design, RF, Power Electronics, PCB Routing and much more

EDABoard: Forum for electronics

Sponsored Content

  • Global supply needs drive increased manufacturing footprint development
  • How to Increase Rotational Capacity for a Retaining Ring
  • Cordis high resolution electronic proportional pressure controls
  • WAGO’s custom designed interface wiring system making industrial applications easier
  • 10 Reasons to Specify Valve Manifolds
  • Case study: How a 3D-printed tool saved thousands of hours and dollars

Design World Podcasts

May 17, 2022
Another view on additive and the aerospace industry
See More >
Engineering Exchange

The Engineering Exchange is a global educational networking community for engineers.

Connect, share, and learn today »

Design World
  • Advertising
  • About us
  • Contact
  • Manage your Design World Subscription
  • Subscribe
  • Design World Digital Network
  • Engineering White Papers
  • LEAP AWARDS

Copyright © 2022 WTWH Media LLC. All Rights Reserved. The material on this site may not be reproduced, distributed, transmitted, cached or otherwise used, except with the prior written permission of WTWH Media
Privacy Policy | Advertising | About Us

Search Design World

  • Home
  • Technologies
    • 3D CAD
    • Electronics • electrical
    • Fastening & Joining
    • Factory automation
    • Linear Motion
    • Motion Control
    • Test & Measurement
    • Sensors
    • Fluid power
  • Learn
    • Ebooks / Tech Tips
    • Engineering Week
    • Future of Design Engineering
    • MC² Motion Control Classrooms
    • Podcasts
    • Videos
    • Webinars
  • LEAP AWARDS
  • Leadership
    • 2022 Voting
    • 2021 Winners
  • Design Guide Library
  • Resources
    • 3D Cad Models
      • PARTsolutions
      • TraceParts
    • Digital Issues
      • Design World
      • EE World
    • Women in Engineering
  • Supplier Listings